\pgfdeclarelayer{layer} % declare layer \pgfsetlayers{layer,main} % set the order of the layers (main is the standard layer)
in the plotting step you can then explicitly plot on a different layer by using the pgfonlayer environment
\begin{pgfonlayer}{layer} \draw[ultra thick] (0.0,0.0) -- ++ (1.0,0.0); \end{pgfonlayer}